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Chloe Sevigny is probably one of the most exciting celebrities in terms of dressing up for red carpet events. With a quirky sense of style that doesn’t follow any Hollywood fashion trends, Chloe can make elegant dresses very elegant, turn sexy ensembles super sexy and can even make the trashiest outfits look cool. So when we heard that Miu Miu chose Sevigny for the brand’s fall 2012 ad campaign, it got us all excited for the collaboration.

Although it Chloe has been rumored to sign on to this role since last month, it was only until we saw the Miu Miu autumn/winter 2012 campaign shot by Mert & Marcus that confirmed the news. Wearing pieces from Miu Miu’s autumn/winter collection, Sevigny rocked a silk pyjama-style pants, a masculine shirt with a checkered tie, clunky printed heels and mismatched makeup, while sipping on a tea cup.

But this isn’t the first time Chloe Sevigny will be fronting the brand. Back in 1996, one of Chloe’s first major modeling gigs was for a Miu Miu shoot taken by Juergen Teller. This time, Miu Miu stated that the campaign was for a “gallery of portraits with a seductive, provocative attitude.”

Other Miu Miu spokespersons/models include Hailee Steinfeld, Selma Blair, Evan Rachel Wood, Kirsten Dunst, Katie Holmes and Mia Wasikowska. Check out Chloe in various Miu Miu outfits throughout the years…

Photos by: Andres Otero/Apega/ FayesVision/WENN.com